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How Pool Algaecide Works: Complete Chemistry Guide 2024

Algae Green Pool Medium 15 minutes reading, varies for application 20 views

What's the science behind how algaecides work in pools?

I've been dealing with recurring algae issues in my 20,000-gallon inground pool and my pool store keeps recommending different algaecides. I've tried copper-based and polyquat algaecides, but I'm curious about the actual chemistry behind how these products work to kill algae.

My current chlorine levels are around 2-3 ppm and pH is 7.4, but I still get green spots forming on the walls every few weeks. The pool guy says algaecides work differently than chlorine, but he couldn't explain exactly how. I'd love to understand the science behind what's happening at the cellular level when algaecide contacts algae, and whether I should be relying more on higher chlorine levels or these specialty chemicals for prevention and treatment.

Dear Eric U.,

Quick Answer

Pool algaecides work by disrupting algae cell walls and metabolic processes to kill and prevent algae growth. However, proper chlorine levels are more effective for treating existing algae problems than algaecides alone.

Tools & Supplies Needed

pool test kit algaecide product measuring cup

Find on Amazon: Polyquat Pool Algaecide , Taylor Pool Test Kit , Liquid Pool Chlorine

Understanding How Pool Algaecides Work

Pool algaecides are specialized chemicals designed to kill and prevent algae growth in swimming pools. They work through different mechanisms depending on their chemical composition, but all aim to disrupt algae's ability to survive and reproduce in your pool water. Understanding how these products work will help you use them more effectively and know when they're actually needed.

Types of Algaecides and Their Mechanisms

Quaternary Ammonium Compounds (Quats)

The most common pool algaecides contain quaternary ammonium compounds, which work by disrupting the cell membranes of algae. These positively charged molecules are attracted to the negatively charged algae cells, where they bind to the cell wall and cause it to rupture. This process kills the algae and releases its contents into the water, which is why you might notice cloudiness after adding quat-based algaecides.

Quat algaecides are effective against most common pool algae types including green algae and some yellow algae strains. However, they can cause foaming if overdosed and may interfere with chlorine effectiveness temporarily.

Copper-Based Algaecides

Copper sulfate and copper complexes work differently by interfering with algae's metabolic processes. Copper ions disrupt photosynthesis and enzyme function within algae cells, effectively starving them of energy. These algaecides are particularly effective against stubborn black algae and persistent yellow algae that resist other treatments.

The downside of copper-based algaecides is the risk of copper staining, especially in pools with low pH or high total dissolved solids. Always test your water chemistry before using copper algaecides and maintain proper pH levels between 7.4-7.6.

Polyquat Algaecides

Polymeric quaternary ammonium compounds represent the premium category of algaecides. They work similarly to regular quats but with longer-lasting effectiveness and reduced foaming potential. Polyquats form a protective film on pool surfaces that continues to prevent algae attachment even after the initial treatment.

The Science Behind Algae Prevention vs. Treatment

It's crucial to understand that algaecides work best as preventive measures rather than primary treatments for active algae blooms. When algae is already established in your pool, the most effective approach is the SLAM method (Shock Level And Maintain) using liquid chlorine.

During an active algae bloom, chlorine demand is extremely high because the algae consume available chlorine as fast as you add it. Algaecides can help weaken the algae, but only sustained high chlorine levels will effectively kill large algae populations and oxidize the organic waste they produce.

Proper Application and Timing

Weekly Maintenance Dosing

For prevention, add algaecide weekly at the manufacturer's recommended maintenance dose, typically 3-4 ounces per 10,000 gallons for most quat-based products. Add the algaecide in the evening after the sun sets to prevent UV degradation and ensure even distribution throughout your circulation system.

Shock Treatment Application

When treating visible algae, use the shock dose rate (usually double the maintenance dose) but always in conjunction with proper chlorination. Add the algaecide first, let it circulate for 2-4 hours, then begin your chlorine shock treatment. Test your free chlorine levels every 2-3 hours and maintain them at shock level based on your CYA (stabilizer) levels.

Chemical Interactions and Compatibility

Algaecides can interact with other pool chemicals, affecting their performance. Quat-based algaecides may temporarily reduce chlorine effectiveness for 24-48 hours after application. This is normal but means you might need to add more chlorine to maintain proper sanitizer levels.

Never mix algaecides with other chemicals. Add them separately with at least 30 minutes between different chemical additions. Always add algaecides to water, never water to algaecides, and pour slowly around the pool perimeter with the pump running for proper circulation.

Limitations and Realistic Expectations

While algaecides are valuable tools in pool maintenance, they have important limitations. They cannot fix underlying water balance issues that allow algae to flourish, such as low chlorine levels, high pH, or excessive organic contamination. If your pool regularly develops algae despite algaecide use, focus on maintaining proper chlorine levels (1-3 ppm free chlorine for most pools) and balanced pH (7.4-7.6).

Algaecides also become less effective in pools with high stabilizer (CYA) levels above 80 ppm, where chlorine efficiency is already compromised. In these situations, partially draining and refilling the pool may be necessary before algaecides can work effectively.

Cost-Effectiveness and Alternatives

Quality algaecides range from $15-60 per bottle depending on type and concentration. While this seems expensive, proper use of algaecides as preventive measures can save money compared to dealing with major algae blooms requiring large amounts of shock and potential professional treatment.

However, the most cost-effective algae prevention remains consistent chlorination and proper water balance. A reliable test kit like the Taylor K-2006 and regular testing will do more to prevent algae than any algaecide alone.

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Tags: #algaecide #pool chemicals #algae prevention #water chemistry